Metal Ion Control the Selective Sensing of Oxalate Anion by Dinuclear Complexes under Indicator Displacement Strategy
Abstract
Two dinuclear complexes of Cu(II) and Zn(II) with bis(dipicolylamine) linked by a para-xylylene bridge, CuL1 and ZnL1 have been synthesized and characterized. Both compounds are applied as metal-based indicator displacement assay (IDA) receptors for anions using bromopyrogallol red (BPG) as sensing indicators in 80/20 (%v/v) acetronitrile/water solution buffered with 10 mM HEPES at pH 7.0. After addition of various anions to the solution of [CuL1•BPG] and [ZnL1•BPG] ensemble, the results showed that only [CuL1•BPG] could discriminate oxalate from other anions obviously resulting in the color change from blue-violet of ensemble to magenta color of free BPG. This result indicates that the nature of metal ion plays a crucial role to control the selective sensing of oxalate in this work. The quantitative detection of oxalate by [CuL1•BPG] ensemble was ranged from 20 – 50 µM, and a correlation coefficient (R2) = 0.995. The detection limit was 20 µM by the naked eye.
Keywords : dinuclear complex ; indicator displacement assay ; oxalate ; naked eye ; ensemble
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